Synlett

Microwave-assisted Suzuki-Miyaura reactions with an insoluble pyridine-aldoxime Pd-catalyst

W Solodenko, U Schoen, J Messinger, A Glinschert…

文献索引：Solodenko, Wladimir; Schoen, Uwe; Messinger, Josef; Glinschert, Anja; Kirschning, Andreas Synlett, 2004 , # 10 p. 1699 - 1702

全文：HTML全文

被引用次数: 53

摘要

Abstract The preparation of a solid Pd (II)-precatalyst and its use in microwave-assisted Suzuki-Miyaura reactions in water is described. The precatalyst is obtained by treatment of 4- pyridine-aldoxime with Na 2 PdCl 4 and is insoluble in organic solvents as well as in water. Its robustness under microwave conditions and its insolubility allows simple reuse in 'teabags'.