Tetrahedron

Carbon—carbon bond formation using manganese (iii) acetate as an electrochemical mediator

R Shundo, I Nishiguchi, Y Matsubara, T Hirashima

文献索引：Shundo, Ryushi; Nishiguchi, Ikuzo; Matsubara, Yoshiharu; Hirashima, Tsuneaki Tetrahedron, 1991 , vol. 47, # 4/5 p. 831 - 840

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被引用次数: 27

摘要

Anodic oxidation in a solution containing a variety of olefins and a small amount of Mn (OAc) 2· 4H2O brought about Mn+ 3-mediated carbon—carbon bond formation, such as efficient carboxymethylation of styrene derivatives to the corresponding γ-aryl-γ-butyrolactones, and selective coupling of active methylene compounds with non-activated monoolefins, unconjugated dienes or 5-arylpent-1-enes.