Journal of the American Chemical Society

Directly observed reductive elimination of aryl halides from monomeric arylpalladium (II) halide complexes

AH Roy, JF Hartwig

文献索引：Roy, Amy H.; Hartwig, John F. Journal of the American Chemical Society, 2003 , vol. 125, # 46 p. 13944 - 13945

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被引用次数: 139

摘要

Monomeric, three-coordinate arylpalladium (II) halide complexes undergo reductive elimination of aryl halide to form free haloarene and Pd (0). Reductive elimination of aryl chlorides, bromides, and iodides were observed upon the addition of P (t-Bu) 3 to Pd [P (t- Bu) 3](Ar)(X)(X= Cl, Br, I). Conditions to observe the equilibrium between reductive elimination and oxidative addition were established with five haloarenes. Reductive ...