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Journal of Organometallic Chemistry

Wurtz-type reductive coupling reaction of primary alkyl iodides and haloorganotins in cosolvent/H 2 O (NH 4 Cl)/Zn media as a route to mixed alkylstannanes and …

D Marton, M Tari

文献索引:Marton, Daniele; Tari, Massimo Journal of Organometallic Chemistry, 2000 , vol. 612, # 1-2 p. 78 - 84

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被引用次数: 7

摘要

Mixed tetra-alkylstannanes R3SnR′(R= Et, n-Pr, n-Bu and R′= Me, Et, n-Pr, n-Bu, n-Pent) and R2SnR′ 2 (R= n-Bu and R′= Me, Et, n-Pr, n-Bu) can be easily prepared in a one-pot synthesis via coupling reaction of alkyl iodides R′ I with R3SnX (X= Cl, I) and R2SnCl2 compounds in cosolvent–H2O (NH4Cl) medium mediated by zinc dust. Coupling also occurs with (Bu3Sn) 2O. It has been verified that reactions are possible only with primary ...

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