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Tetrahedron letters

Oxidation of α, β-enones and alkenes with oxone and sodium halides: A convenient laboratory preparation of chlorine and bromine

RK Dieter, LE Nice, SE Velu

文献索引:Dieter, R. Karl; Nice, Lois E.; Velu, Sadanandan E. Tetrahedron Letters, 1996 , vol. 37, # 14 p. 2377 - 2380

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被引用次数: 95

摘要

Mixtures of oxone and sodium chloride or sodium bromide afford solutions of chlorine or bromine, respectively. These solutions effectively add chlorine and bromine to α, β-enones and alkenes. The method affords improved yields of 3-alkyl-2-halo-2-cycloalkenones which are sometimes difficult to prepare.