Palladium-catalyzed direct arylation of azine and azole N-oxides: Reaction development, scope and applications in synthesis

…, M Bertrand-Laperle, E Villemure…

文献索引：Campeau, Louis-Charles; Stuart, David R.; Leclerc, Jean-Philippe; Bertrand-Laperle, Megan; Villemure, Elisia; et al. Journal of the American Chemical Society, 2009 , vol. 131, p. 3291 - 3306

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被引用次数: 277

摘要

Palladium-catalyzed direct arylation reactions are described with a broad range of azine and azole N-oxides. In addition to aspects of functional group compatibility, issues of regioselectivity have been explored when nonsymmetrical azine N-oxides are used. In these cases, both the choice of ligand and the nature of the azine substituents play important roles in determining the regioisomeric distribution. When azole N-oxides are employed, ...