ChemSusChem

Sequential Continuous Flow Processes for the Oxidation of Amines and Azides by using HOF⋅ MeCN

CB McPake, CB Murray, G Sandford

文献索引：McPake, Christopher B.; Murray, Christopher B.; Sandford, Graham ChemSusChem, 2012 , vol. 5, # 2 p. 312 - 319

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被引用次数: 7

摘要

Abstract The generation and use of the highly potent oxidising agent HOF⋅ MeCN in a controlled single continuous flow process is described. Oxidations of amines and azides to corresponding nitrated systems by using fluorine gas, water and acetonitrile by sequential gas–liquid/liquid–liquid continuous flow procedures are reported.