Chemical Communications 2005-04-07

The novel and efficient direct synthesis of N,O-acetal compounds using a hypervalent iodine(III) reagent: an improved synthetic method for a key intermediate of discorhabdins.

Yu Harayama, Masako Yoshida, Daigo Kamimura, Yasuyuki Kita

文献索引：Chem. Commun. (Camb.) (13) , 1764-6, (2005)

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摘要

The use of hypervalent iodine(III) reagents allowed us to develop the novel and efficient direct synthesis of N,O-acetal compounds via the oxidative fragmentation reaction of alpha-amino acids or alpha-amino alcohols; furthermore, we succeeded in developing an improved synthesis of the key intermediate of discorhabdins.