Prussian Blue as an Efficient Catalyst for Rate Accelerations in the Transesterification of β-Ketoesters

P Srinivas, KC Rajanna, G Krishnaiah…

文献索引：Srinivas; Rajanna; Krishnaiah; Kumar, M. Satish; Reddy, J. Narender Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2014 , vol. 44, # 8 p. 1212 - 1220

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摘要

Prussian blue triggered transesterification of ethylacetoacetate with various alcohols underwent efficiently. The reaction is mild, eco-friendly, and selective with good yields. The proposed reaction pathway depicts the formation of an intermediate by the interaction of β- ketoesters with catalytic site of the Prussian blue, followed by nucleophilic attack of the alcohol at the electrophilic center followed by successive elimination of the proton to give ...