前往化源商城

举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

The chemistry of thujone. XVI. Versatile and efficient routes to safronitrile, β-cyclogeranonitrile, β-cyclocitral, damascones, and their analogues

…, PJ Gunning, RG Clewley, J Somerville…

文献索引：Kutney, James P.; Gunning, Philip J.; Clewley, Robin G.; Somerville, John; Rettig, Steven J. Canadian Journal of Chemistry, 1992 , vol. 70, # 7 p. 2094 - 2114

全文：HTML全文

被引用次数: 7

摘要

Thujone, a waste by-product of the Canadian forest industry, has been utilized as a starting material to develop a versatile synthetic route to the damascones (rose oil ketones) and related analogues. The synthetic sequence provides a route to β-cyclocitral (45), the latter having been previously converted to β-damascone (2). In addition, thujone-derived intermediates are converted to β-damascenone (48) and to intermediates that can be ...

2,6-二甲基环己酮 (异构体的混合物)结构式

2,6-二甲基环己酮 (异构体的混合物)

碘甲烷结构式

~%

2,2,6-三甲基环庚烷结构式

2,2,6-三甲基环庚烷

2,2,6,6-四甲基环己酮结构式

2,2,6,6-四甲基环己酮

未登录结构式

~27%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

(1S,5S) 4,4-Dimethyl-1-(1-methylethyl)-bicyclo[3.1.0]hexan-3-one结构式

(1S,5S) 4,4-Dim...

~%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

2,2,6-三甲基环庚烷结构式

2,2,6-三甲基环庚烷

~%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

1-hydroxy-2,2,6-trimethyl-cyclohexanecarbonitrile结构式

1-hydroxy-2,2,6...

~%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

2,4,4-Trimethylcyclohex-2-en-1-one-3-carbonitrile结构式

2,4,4-Trimethyl...

~%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

1-isopropyl-2,4,4-trimethyl-bicyclo[3.1.0]hexan-3-one结构式

1-isopropyl-2,4...

~%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

1-isopropyl-2,4,4-trimethyl-bicyclo[3.1.0]hexan-3-one结构式

1-isopropyl-2,4...

~%

2,6,6-Trimethylcyclohexa-1,3-dien-1-ylcarbonitrile结构式

2,6,6-Trimethyl...

2,6,6-trimethylcyclohexene-1-carbonitrile结构式

2,6,6-trimethyl...

~91%

β-环柠檬醛结构式

β-环柠檬醛

未登录结构式

~%

β-环柠檬醛结构式

β-环柠檬醛

1-hydroxy-2,2,6-trimethyl-cyclohexanecarbonitrile结构式

1-hydroxy-2,2,6...

~%

β-环柠檬醛结构式

β-环柠檬醛

(1S,5S) 4,4-Dimethyl-1-(1-methylethyl)-bicyclo[3.1.0]hexan-3-one结构式

(1S,5S) 4,4-Dim...

~%

β-环柠檬醛结构式

β-环柠檬醛

2,2,6-三甲基环庚烷结构式

2,2,6-三甲基环庚烷

~%

β-环柠檬醛结构式

β-环柠檬醛

2,4,4-Trimethylcyclohex-2-en-1-one-3-carbonitrile结构式

2,4,4-Trimethyl...

~%

β-环柠檬醛结构式

β-环柠檬醛

3-Hydroxy-2,6,6-trimethyl-1-cyclohexene-1-carbonitrile结构式

3-Hydroxy-2,6,6...

~%

β-环柠檬醛结构式

β-环柠檬醛

1-isopropyl-2,4,4-trimethyl-bicyclo[3.1.0]hexan-3-one结构式

1-isopropyl-2,4...

~%

β-环柠檬醛结构式

β-环柠檬醛

1-isopropyl-2,4,4-trimethyl-bicyclo[3.1.0]hexan-3-one结构式

1-isopropyl-2,4...

~%

β-环柠檬醛结构式

β-环柠檬醛

(1S,5S) 4,4-Dimethyl-1-(1-methylethyl)-bicyclo[3.1.0]hexan-3-one结构式

(1S,5S) 4,4-Dim...

~%

α-香叶腈结构式

2,2,6-三甲基环庚烷结构式

2,2,6-三甲基环庚烷

~%

α-香叶腈结构式

2,6,6-trimethylcyclohexene-1-carbonitrile结构式

2,6,6-trimethyl...

~%

α-香叶腈结构式

2,4,4-Trimethylcyclohex-2-en-1-one-3-carbonitrile结构式

2,4,4-Trimethyl...

~%

α-香叶腈结构式

1-hydroxy-2,2,6-trimethyl-cyclohexanecarbonitrile结构式

1-hydroxy-2,2,6...

~%

α-香叶腈结构式

3-Hydroxy-2,6,6-trimethyl-1-cyclohexene-1-carbonitrile结构式

3-Hydroxy-2,6,6...

~%

α-香叶腈结构式

1-isopropyl-2,4,4-trimethyl-bicyclo[3.1.0]hexan-3-one结构式

1-isopropyl-2,4...

~%

α-香叶腈结构式

1-isopropyl-2,4,4-trimethyl-bicyclo[3.1.0]hexan-3-one结构式

1-isopropyl-2,4...

~%

α-香叶腈结构式

未登录结构式

~%

2,6,6-trimethylcyclohexene-1-carbonitrile结构式

2,6,6-trimethyl...

α-香叶腈结构式

(E)-1-(2,6,6-Trimethylcyclohexa-1,3-dienyl)but-2-en-1-ol结构式

(E)-1-(2,6,6-Tr...

~99%

大马士酮结构式

Alkylation of enolates with triflates

[Bates, Robert B.; Taylor, Stuart R. Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4469 - 4470]

Bibliographie normande 1981

[Haller; Cornubert Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 367]

Bibliographie normande 1981

[Haller; Cornubert Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 367]

Bibliographie normande 1981

[Haller; Cornubert Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 367]

Bibliographie normande 1981

[Haller; Cornubert Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 367]