Chemoenzymatic Total Synthesis of a Naturally Occurring (5??5′)/(8′??O??4 ″) Dehydrotrimer of Ferulic Acid
…, AL Flourat, MMM Cannet, PH Ducrot…
文献索引：Mouterde, Louis M. M.; Flourat, Amandine L.; Cannet, Molly M. M.; Ducrot, Paul-Henri; Allais, Florent European Journal of Organic Chemistry, 2013 , # 1 p. 173 - 179
Abstract The cross-linking of plant cell walls by ferulate dehydrodimerization reactions is well established. Recently, a (5-5′)/(8′-O-4 ″) dehydrotrimer of ferulic acid (A) was isolated from alkali extracts of maize bran. Its structure was elucidated on the basis of an extensive structural analysis (UV, MS, 1D and 2D NMR). This first identified ferulic acid dehydrotrimer has revealed that parietal polysaccharide chains can be more extensively ...
