Tetrahedron

Mechanistic and synthetic aspects of amine oxidations promoted by 3-methyl-5-ethyllumiflavinium perchlorate

SE Hoegy, PS Mariano

文献索引：Hoegy, Susan E.; Mariano, Patrick S. Tetrahedron, 1997 , vol. 53, # 14 p. 5027 - 5046

全文：HTML全文

被引用次数: 26

摘要

Preparative and kinetic aspects of the chemistry of 3-methyl-5-ethyllumiflavinium perchlorate (1) with primary and secondary amines have been investigated. Reactions of 1 with primary and secondary amines leads to rapid production of modestly stable C4a-adducts. The rates of these processes, determined by stopped-flow kinetic methods, parallel amine nucleophilicities. The C4a-adducts undergo benzylamine promoted elimination reactions ...