Soluble Gold and Palladium Complexes Heterogenized on MCM??41 Are Effective and Versatile Catalysts

C González??Arellano, A Corma…

文献索引：Gonzalez-Arellano, Camino; Corma, Avelino; Iglesias, Marta; Sanchez, Felix European Journal of Inorganic Chemistry, 2008 , # 7 p. 1107 - 1115

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被引用次数: 20

摘要

Abstract Chiral Schiff base–gold and–palladium complexes were immobilized on ordered mesoporous silica supports (MCM-41), and their catalytic hydrogenation ability is studied and compared with that of their homogeneous counterparts. The high accessibility introduced by the structure of the supports allows the preparation of highly efficient immobilized catalysts with TOFs of up to 6000 h–1 for the hydrogenation of diethyl ...