Chemistry Letters

Dealuminoxylation of aluminum allyl or benzyl alkoxides and deoxygenation of allyl ethers by lithium aluminum hydride in the presence of titanium catalyst.

F Sato, Y Tomuro, H Ishikawa, T Oikawa, M Sato

文献索引：Sato, Fumie; Tomuro, Yasuji; Ishikawa, Hiroaki; Oikawa, Takeshi Chemistry Letters, 1980 , p. 103 - 106

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被引用次数: 9

摘要

Various aluminum allyl and benzyl alkoxides and allyl ethers undergo hydrogenolysis by LiAlH 4 in the presence of a catalytic amount of TiCl 4 or Cp 2 TiCl 2. Thus, the present reaction provides a convenient method for replacing oxygen-containing functional groups at the allylic or benzylic position by hydrogen.