The yields of some aliphatic tertiary Grignard reagents and the limits of their usefulness as synthetic reagents

FC Whitmore, DE Badertscher

文献索引：Whitmore; Badertscher Journal of the American Chemical Society, 1933 , vol. 55, p. 1560

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被引用次数: 22

摘要

Researches on rearrangements being conducted in this Laboratory required a variety of compounds containing the grouping K3CC (OH) RL. 2 in which R represents various alkyl groups and R'represents alkyl or hydrogen. The preparation of these substances by means of the Grignard reaction presented two uncertainties,(1) the decreased yield of Grignard reagents of higher molecular weight especially from tertiary halides which lost! halogen ...