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Tetrahedron

The asymmetric Baylis-Hillman reaction as a template in organic synthesis

LJ Brzezinski, S Rafel, JW Leahy

文献索引:Brzezinski, Linda Joy; Rafel, Sara; Leahy, James W. Tetrahedron, 1997 , vol. 53, # 48 p. 16423 - 16434

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被引用次数: 54

摘要

The Baylis-Hillman reaction of camphor-based acrylates has been demonstrated to result in the formation of products with high optical purity. A model that explains these results and the use of these products in the formation of anti aldol adducts is discussed. ... The Baylis-Hillman reaction of camphor-based acrylates has been demonstrated to result in the formation of products with high optical purity. A model that explains these results and the use of these products ...