Tetrahedron letters

CO 2 anion–radical in organic carboxylations

MD Otero, B Batanero, F Barba

文献索引：Otero, M. Dolores; Batanero, Belen; Barba, Fructuoso Tetrahedron Letters, 2006 , vol. 47, # 13 p. 2171 - 2173

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被引用次数: 16

摘要

This letter shows a first approximation to the use of CO2 anion–radical in the obtention of α- methyl and α-ethylcyanoacetic acids from propionitrile and butyronitrile, respectively, through a paired electrochemical reaction with CO2. The electrosynthesis of α-chloro- phenylacetic acid from benzyl chloride and phenylacetic acid from toluene by another proposed pathway is also discussed.