Helvetica chimica acta

Chlorine Dioxide as an Electron??Transfer Oxidant of Olefins. Preliminary Communication

C Rav??Acha, S Sarel

文献索引：Rav-Acha, Chaim; Choshen, Ehud; Sarel, Shalom Helvetica Chimica Acta, 1986 , vol. 69, p. 1728 - 1733

被引用次数: 1

摘要

Abstract The kinetics and product studies of oxidation of eight olefins 1-8 by ClO 2 in H 2 O in the pH range 3-7 are described. The reaction is faster as the pH decreases. At pH< 4, ClO 2 reacts equimolarly with olefins to yield isomeric mixtures of chlorohydrines and 1, 2- dioxygenated products, following the equation:

~5%

详细

~26%

详细

~22%

详细

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