Journal of the American Chemical Society

SYNTHESES WITH TRIARYLVINYLMAGNESIUM BROMIDES. PENTAARYLALLYL ALCOHOLS

CF Koelsch

文献索引：Koelsch Journal of the American Chemical Society, 1932 , vol. 54, p. 3384,3387

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被引用次数: 11

摘要

The interest attaching to compounds of trivalent carbon in which the methane carbon atom bears two aryl groups and one unsaturated aliphatic group has led to the investigation described in this paper. The object of this research has been to synthesize a pentaarylallyl radical, R2GCR-CRt-, and to compare the behavior of this substance with that of the less highly phenylated tetraarylallyl radicals, R&= CH-CR2-, of Ziegler. Although this object ...