Abnormal Grignard Reactions. XII. 1 Sterically Hindered Aliphatic Carbonyl Compounds. II. 1 Ketones Containing the Dineopentylcarbinyl Group

FC Whitmore, CT Lester

文献索引：Whitmore; Lester Journal of the American Chemical Society, 1942 , vol. 64, p. 1247,1250

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被引用次数: 1

摘要

A rather systematic study of sterically hindered ketones of the aromatic series, especially those containing the mesityl group, has been made. 3 Aliphatic sterically hindered ketones, however, have received attention only recently.'The investigations have been concerned mainly with (1) the effect of different adjacent groups on the reactivity of the carbonyl and (2) the preparations and reactions of the halomagnesium enolates of these ketones.