Uncommonly Easy Nitrodealkylation in Nitration of para-Substituted Benzylcyclopropanes

…, RA Gazzaeva, BP Archegov, EV Trofimova…

文献索引：Mochalov; Fedotov; Gazzaeva; Archegov; Trofimova; Zefirov Russian Journal of Organic Chemistry, 2001 , vol. 37, # 6 p. 889 - 890

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被引用次数: 1

摘要

This process is usually a side reaction, and conversion of dialkylbenzenes into the corresponding para-or ortho-alkylnitrobenzenes does not exceed 10317%. Most often the nitrodealkylation occurs at nitration of dialkylbenzenes containing isopropyl [133] or tert- butyl [3, 4] groups. As to replacement with the nitro group of methyl or ethyl, it was observed only once in nitration of para-methyl-and para-ethylphenylcyclopropanes [3]. We found ...