Journal of the American Oil Chemists' Society

Enzymatic esterification of glycerol III. Lipase-catalyzed synthesis of regioisomerically pure 1, 3-sn-diacylglycerols and 1 (3)-rac-monoacylglycerols derived from …

C Waldinger, M Schneider

文献索引：Waldinger; Schneider JAOCS, Journal of the American Oil Chemists' Society, 1996 , vol. 73, # 11 p. 1513 - 1519

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被引用次数: 54

摘要

Abstract Lipases that display high regioselectivities and broad substrate tolerance were used as catalysts for the efficient esterification of glycerol under the conditions of irreversible acyl transfer. A variety of unsaturated fatty acids, such as oleic, linoleic, erucic, ricinolic, hydroxystearic and coriolic acid, were used for this purpose in the form of their vinyl esters. Suitable biocatalysts were chosen on the basis of systematic screening experiments ...