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Synthetic Communications

SOCl2/β-cyclodextrin: A new and efficient catalytic system for Beckmann rearrangement and dehydration of aldoximes under aqueous condition

D Patil, D Dalal

文献索引:Patil, Dipak; Dalal, Dipak Synthetic Communications, 2013 , vol. 43, # 1 p. 118 - 128

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被引用次数: 5

摘要

A great effort has been made to manufacture amides and transform ketoximes to amides, known as the Beckmann rearrangement, a very important and useful transformation in synthetic chemistry. [ 1 1. Croig , D. ; Trost , BM ; Fleming , I. ; Ley , SV In Comprehensive Organic Synthesis ; Pergamon Press : Oxford , 1991 ; vol. 7 , pp. 689 – 702 . [CrossRef] View all references ] Conventional Beckmann rearrangement usually requires relatively high temperature and large amounts ...