Higher alkyl monoethers of mono-to tetraethylene glycol2a, b

AN Wrigley, AJ Stirton…

文献索引：Wrigley,A.N. et al. Journal of Organic Chemistry, 1960 , vol. 25, p. 439 - 444

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被引用次数: 27

摘要

The mono-n-dodecyl, tetradecyl, hexadecyl, and octadecyl ethers of mono-to tetraethylene glycol, R (OCH&H*) iOH, were synthesized from alkyl halides or tosylates or by alkali- catalyzed reaction of alcohols with ethylene oxide. In the dodecyl, tetradecyl, and hexadecyl series, freezing-point minima occurred ati= 3. The distribution of products in oxyethylation of tetradecanol followed the equations of Weibull and Nycander, with a distribution constant ...