Tetrahedron Letters

Photolytic rearrangement of phosphorus azide: evidence for a transient metaphosphonimidate.

G Bertrand, JP Majoral, A Baceiredo

文献索引：Bertrand, Guy; Majoral, Jean-Pierre; Baceiredo, Antoine Tetrahedron Letters, 1980 , vol. 21, p. 5015 - 5018

被引用次数: 29

摘要

The cyclic derivative (13)(lg) was obtained when photolysis was carried out withpinacol. Howewer the use of ethylene glycol allowed us to caracterize monoaddition product (14) which is slowly converted to dioxaphospholane (l5)(20). Note that the rate enhancementof the reaction (14) to (15) is temperature sensitive.--

详细

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Part I: The Development of the Catalytic Wittig Reaction

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