Phosphine-and thiophosphorane-amine ligands: Lithiation and coordination to Rh (I)

E Payet, A Auffrant, XF Le Goff, P Le Floch

文献索引：Payet, Elina; Auffrant, Audrey; Le Goff, Xavier F.; Floch, Pascal Le Journal of Organometallic Chemistry, 2010 , vol. 695, # 10-11 p. 1499 - 1506

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被引用次数: 12

摘要

A series of phosphine-amine and thiophosphorane-amine ligands (PR2 (X) CH2NHR′, X= lone pair, S, R= Ph, Cy, R′= tBu, Ph) differing by the nature of the phosphorus and nitrogen substituents were synthesized. Their lithiation, in order to generate the corresponding amido ligand mainly led to dissociation with formation of phosphide or thiophosphinite anion and imine. DFT calculations confirmed that this pathway is in most cases thermodynamically ...