ChemSusChem

Catalytic Transfer Hydrogenation/Hydrogenolysis for Reductive Upgrading of Furfural and 5??(Hydroxymethyl) furfural

D Scholz, C Aellig, I Hermans

文献索引：Scholz, David; Aellig, Christof; Hermans, Ive ChemSusChem, 2014 , vol. 7, # 1 p. 268 - 275

全文：HTML全文

被引用次数: 69

摘要

Abstract The sequential transfer hydrogenation/hydrogenolysis of furfural and 5- hydroxymethylfurfural to 2-methylfuran and 2, 5-dimethylfuran was studied over in situ reduced, Fe 2 O 3-supported Cu, Ni, and Pd catalysts, with 2-propanol as hydrogen donor. The remarkable activity of Pd/Fe 2 O 3 in both transfer hydrogenation/hydrogenolysis is attributed to a strong metal–support interaction. Selectivity towards hydrogenation, ...