2-(Trifluoroacetyl) imidazoles, 2-Trifluoroacetyl-1, 3-thiazoles, and 2-Trifluoroacetyl-1, 3-oxazoles
…, DM Panov, II Pervak, EV Zarudnitskii, OV Shishkin…
文献索引：Khodakovskiy, Pavel V.; Volochnyuk, Dmitriy M.; Panov, Dmitriy M.; Pervak, Igor I.; Zarudnitskii, Evgenij V.; Shishkin, Oleg V.; Yurchenko, Aleksandr A.; Shivanyuk, Alexander; Tolmachev, Andrey A. Synthesis, 2008 , # 6 p. 948 - 956
Abstract A facile method of trifluoroacylation of imidazoles, 1, 3-thiazoles, and 1, 3-oxazoles with trifluoroacetic anhydride resulted in a set of heterocyclic trifluoromethyl-containing ketones. Unlike common ketones, these compounds form stable hydrates and enter into noncatalytic ene reactions with terminal olefins affording the corresponding allyl alcohols.
