Hydroxylation of chlorotoluenes and cresols: a pulse radiolysis, laser flash photolysis, and product analysis study

SC Choure, MMM Bamatraf, BSM Rao…

文献索引：Choure; Bamatraf; Rao; Das; Mohan; Mittal Journal of Physical Chemistry A, 1997 , vol. 101, # 51 p. 9837 - 9845

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被引用次数: 32

摘要

The reactions of OH, O-and SO4-with 2-, 3-, and 4-cresols were studied by pulse radiolysis, laser flash photolysis, and product analysis techniques. The rates of OH reaction with cresols are very high (k≈ 1× 1010 M-1 s-1), whereas O-was found to be less reactive (k≈ 2.4× 109 M-1 s-1). The second-order rate constants for SO4-reaction with cresols are in the range (3-6)× 109 M-1 s-1. The transient absorption spectra measured in OH reaction ...