Synthesis

Aminomethylation of Functionalized Organozinc Reagents and Grignard Reagents Using Immonium Trifluoroacetates

N Millot, C Piazza, S Avolio, P Knochel

文献索引：Millot, Nicolas; Piazza, Claudia; Avolio, Salvatore; Knochel, Paul Synthesis, 2000 , # 7 p. 941 - 948

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被引用次数: 33

摘要

Abstract: New immonium trifluoroacetates 1 and 2 react readily with functionalized organozinc or magnesium reagents leading to the corresponding aminomethylated products of type 5 and 7. The resulting bis-allylamines were deallylated leading to primary amines. Key words: organometallic reagents, zinc, magnesium, aminomethylation, primary amines, deprotection