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Free radical and nitroxide mediated polymerization of hydroxy–functional acrylates prepared via lipase–catalyzed transacylation reactions

D Popescu, R Hoogenboom, H Keul…

文献索引:Popescu, Dragos; Hoogenboom, Richard; Keul, Helmut; Moeller, Martin Journal of Polymer Science, Part A: Polymer Chemistry, 2010 , vol. 48, # 12 p. 2610 - 2621

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被引用次数: 14

摘要

Abstract 3-Hydroxypropyl acrylate, 4-hydroxybutyl acrylate, 2-methyl-3-hydroxypropyl acrylate, 2-hydroxypropyl acrylate, neopentyl glycol acrylate, glyceryl acrylate, and dihydroxyhexyl acrylate were prepared via transacylation reaction of methyl acrylate with diols and triols catalyzed by Candida antarctica lipase B. After removal of the enzyme by filtration and the methyl acrylate by distillation, the monomers were polymerized via free ...