A novel synthesis of branched high-molecular-weight (C40+) long-chain alkanes

…, RG Bergosh, MS Meier, RMK CARLSON

文献索引：Lehmler, Hans-Joachim; Bergosh, Robert G.; Meier, Mark S.; Carlson, Robert M. K. Bioscience, Biotechnology and Biochemistry, 2002 , vol. 66, # 3 p. 523 - 531

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被引用次数: 2

摘要

Many biological and geochemical questions remain concerning the structures, functions, and properties of naturally occurring high-molecular-weight (C40+) alkanes with various mid- chain alkylation patterns. Above C40, these alkanes are exceedingly difficult to separate and purify, and syntheses can be blocked by the low solubility of intermediates. To overcome these problems, a facile three-step synthesis employing the alkylation of 1, 3-dithiane with ...