Efficient and selective catalytic oxidative cleavage of α-hydroxy ketones using vanadium-based HPA and dioxygen

…, F Launay, A Atlamsani, JM Brégeault

文献索引：El Aakel; Launay; Atlamsani; Bregeault Chemical Communications, 2001 , # 21 p. 2218 - 2219

全文：HTML全文

被引用次数: 23

摘要

The combination of H3+ n [PMo12− nVnO 40]· aq (HPA-n, n= 3) and dioxygen provides a clean and regioselective reagent for the homolytic cleavage of various representative α- hydroxy ketones (primary to tertiary) and turns out to be as efficient for the catalytic ring opening of chiral natural products.