Journal of the American Chemical Society

The Acid-catalyzed Reaction of Alkyl Azides upon Carbonyl Compounds1

JH Boyer, J Hamer

文献索引：Boyer; Hamer Journal of the American Chemical Society, 1955 , vol. 77, p. 951,953

被引用次数: 107

摘要

11 I_ ArCHO+ RCHENH 111 I_ ArCONHCH2R ganic azides.'From a primary alkyl azide (RCH2-Na) and the conjugate acid of an aldehyde, apparently an adduct was formed which subsequently fied from the reaction in the prksence of sulfuric acid was a~ etanilide,~ obtained in 2% yield. A general reaction between alkyl azides and carbonyl compounds in the presence of a strong acid now has been demonstrated; from aromatic aldehydes the ...

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