The Preparation of Chlorides from Certain Aliphatic Branched Chain Secondary Carbinols1, 2

FC Whitmore, F Johnston

文献索引：Whitmore; Johnston Journal of the American Chemical Society, 1938 , vol. 60, p. 2266

全文：HTML全文

被引用次数: 15

摘要

BY FRANK C. WHITMORE AND FRANKLIN JOHNSTON drogen chloride below 20'for ten weeks. The phosphorus trichloride gave only a phosphite. The other methods gave t-amyl chloride with only traces of material which might contain the secondary chloride. The low temp, erature treatment with hydrogen chloride repeatedly gave yields of over 90% of t-amyl chloride. This method was adopted as standard procedure with the other alcohols studied. ...