前往化源商城

Chemical Communications 2013-01-21

Three-component access to pyrroles promoted by the CAN-silver nitrate system under high-speed vibration milling conditions: a generalization of the Hantzsch pyrrole synthesis.

Verónica Estévez, Mercedes Villacampa, J Carlos Menéndez

文献索引:Chem. Commun. (Camb.) 49(6) , 591-3, (2013)

全文:HTML全文

摘要

A sequential multicomponent process involving the high-speed vibration milling of ketones with N-iodosuccinimide and p-toluenesulfonic acid, followed by addition of a mixture of primary amines, β-dicarbonyl compounds, cerium(IV) ammonium nitrate and silver nitrate afforded polysubstituted, functionalized pyrroles. This one-pot, solid-state process can be considered as the coupling of an α-iodoketone preparation with a general version of the classical Hantzsch pyrrole synthesis.

相关化合物

结构式 名称/CAS号 全部文献
对甲苯磺酸钠 结构式 对甲苯磺酸钠
CAS:657-84-1
硝酸银标准溶液 结构式 硝酸银标准溶液
CAS:7761-88-8
铯 结构式
CAS:7440-46-2
对甲苯磺酸一水合物 结构式 对甲苯磺酸一水合物
CAS:6192-52-5
对甲苯磺酸银 结构式 对甲苯磺酸银
CAS:16836-95-6
对甲苯磺酸锌 结构式 对甲苯磺酸锌
CAS:13438-45-4
N-碘代丁二酰亚胺 结构式 N-碘代丁二酰亚胺
CAS:516-12-1