The Journal of organic chemistry

A new approach for oxygenation using nitric oxide under the influence of N-hydroxyphthalimide

M Eikawa, S Sakaguchi, Y Ishii

文献索引：Eikawa, Masahiro; Sakaguchi, Satoshi; Ishii, Yasutaka Journal of Organic Chemistry, 1999 , vol. 64, # 13 p. 4676 - 4679

全文：HTML全文

被引用次数: 31

摘要

An approach for partial oxygenation through a carbocation as an intermediate was successfully developed by using nitric oxide under the influence of N-hydroxyphthalimide. Thus, a variety of benzylic ethers were converted into the corresponding partially oxidized compounds, which are difficult to prepare by conventional methods, in high yields. For example, the reaction of phthalane with NO in the presence of a catalytic amount of NHPI ...