Selective conversion of C= N bonds to their corresponding carbonyl compounds by the tribromoisocyanuric acid/wet SiO2 system as a novel reagent

D Habibi, MA Zolfigol, AR Faraji, P Rahmani

文献索引：Habibi, Davood; Zolfigol, Mohammad Ali; Faraji, Ali Reza; Rahmani, Payam Monatshefte fur Chemie, 2012 , vol. 143, # 5 p. 809 - 814

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被引用次数: 4

摘要

Abstract Tribromoisocyanuric acid/wet SiO 2 was used for the conversion of C= N bonds to their corresponding carbonyl compounds in oximes, semicarbazones, azines, and Schiff bases. The interesting feature of this system is that in those oximes, semicarbazones, azines, and Schiff bases which have conjugated or unconjugated C= C bonds, the C= N bond will selectively change to the relevant C= O bond while the conjugated or ...