Gaseous Nitrogen Dioxide for Sustainable Oxidative Deprotection of Trimethylsilyl Ethers

…, MR Naimi-Jamal, MG Dekamin, G Kaupp

文献索引：Javaheri, Mehdi; Naimi-Jamal, M. Reza; Dekamin, Mohammad G.; Kaupp, Gerd Phosphorus, Sulfur and Silicon and the Related Elements, 2012 , vol. 187, # 1 p. 142 - 148

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被引用次数: 2

摘要

In this study, trialkylsilyl ethers of indispensable protected alcohols are oxidatively deprotected in neat form with gaseous nitrogen dioxide (NO 2 ). Quantitative yields of aldehydes or ketones are obtained without the necessity of chromatography. The byproducts, nitrogen monoxide, anhydrous nitric acid, and hexamethyldisiloxane, can be quantitatively separated by evaporation and distillation in closed systems for recycling or further use. The direct new method supersedes the ...