Highly reactive and regenerable fluorinating agent for oxidative fluorination of aromatics

KM Janmanchi, WR Dolbier, Jr

文献索引：Janmanchi, Krishna Murthy; Dolbier Jr., William R. Organic Process Research and Development, 2008 , vol. 12, # 2 p. 349 - 354

全文：HTML全文

被引用次数: 15

摘要

A newly synthesized copper aluminum fluoride of nominal composition CuAl 2F 8 exhibits excellent reactivity towards direct oxidative fluorination of aromatic compounds, as well as fluorodechlorination of chloroaromatics. The spent CuAl 2F 8 reagent can be regenerated by treatment with O 2 and HF, and the fluorination process has been demonstrated to retain high conversions through 20 reaction cycles. The main advantages of this new process ...

~21%

详细

~63%

~12%

~6%

~11%

~9%

~38%

详细

~12%

~9%

~6%

~57%

Mechanistic Studies on Fluorobenzene Synthesis from 1, 1-Dif...

[Tojo, Masahiro; Fukuoka, Shinsuke; Tsukube, Hiroshi Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 3 p. 333 - 340]

A series of NiM (M= Ru, Rh, and Pd) bimetallic catalysts for...

[Chatterjee, Maya; Ishizaka, Takayuki; Suzuki, Akira; Kawanami, Hajime Chemical Communications, 2013 , vol. 49, # 40 p. 4567 - 4569]

Electroreductive dehalogenation of fluorobenzenes

[Kariv-Miller, Essie; Vajtner, Zlatko Journal of Organic Chemistry, 1985 , vol. 50, # 9 p. 1394 - 1399]

Aryl fluorides from the reaction of boron trifluoride with a...

[Meio, Giuseppe V. De; Pinhey, John T. Journal of the Chemical Society, Chemical Communications, 1990 , # 15 p. 1065 - 1066]