Inorganica Chimica Acta

Characterization of soluble [RuCl2P2] 2 (P= PPh3), a species which has been postulated to be present in solutions of RuCl2P3; its synthesis from various Ru …

RCJ Vriends, G van Koten, K Vrieeze

文献索引：Vriends, Rob. C. J.; Koten, Gerard van; Vrieze, Kees Inorganica Chimica Acta, 1978 , vol. 26, p. L29 - L31

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被引用次数: 16

摘要

The importance of the 14electron species “R&l2-PZ”(I)[l] is obvious from its key position in mechanisms proposed for processes catalyzed by RuC12Ps [2]. Since I has never been isolated nor observed spectroscopically its existence has been inferred from the observation by 3'P-NMR spectroscopy of a species, which has been postulated to be “(RuC~~ P~)~”(II), in solutions of RuC12P3 (III)[3, 41. Route 1 as well as route 2 can account for the ...