Journal of Organometallic Chemistry

Improved synthetic route to potassium silyl using crown ethers, potassium, and silane and its use to prepare methylsilane and disilylmethane

BF Fieselmann, CR Dickson

文献索引：Fieselmann, Benjamin F.; Dickson, C. Robert Journal of Organometallic Chemistry, 1989 , vol. 363, p. 1 - 6

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被引用次数: 3

摘要

Abstract The time for the reaction between K and SiH 4 in glyme is reduced from months to hours by addition of 18-crown-6 to form [K (18-crown-6)] SiH 3. The usefulness of the reaction to prepare the SiH− 3 anion as a synthetic intermediate is demonstrated by the ...