Zinc-catalyzed nucleophilic substitution reaction of chlorosilanes with organomagnesium reagents

K Murakami, H Yorimitsu, K Oshima

文献索引：Murakami, Kei; Yorimitsu, Hideki; Oshima, Koichiro Journal of Organic Chemistry, 2009 , vol. 74, # 3 p. 1415 - 1417

全文：HTML全文

被引用次数: 39

摘要

Zinc-catalyzed nucleophilic substitution reactions of chlorosilanes with organomagnesium reagents afford various tetraorganosilanes under mild reaction conditions. The reactions can be performed on large scale and allow efficient preparation of functionalized tetraorganosilanes.

13154-24-0

三异丙基氯硅烷

~89%

~71%

~0%

Rhodium (II)-Catalyzed Stereoselective Synthesis of Allylsil...

[Guptill, David M.; Cohen, Carolyn M.; Davies, Huw M. L. Organic Letters, 2013 , vol. 15, # 24 p. 6120 - 6123]

Kinetics of the reactions of allylsilanes, allylgermanes, an...

[Hagen, Gisela; Mayr, Herbert Journal of the American Chemical Society, 1991 , vol. 113, # 13 p. 4954 - 4961]

Copper-catalyzed arylation of chlorosilanes with Grignard re...

[Morita, Eiji; Murakami, Kei; Iwasaki, Masayuki; Hirano, Koji; Yorimitsu, Hideki; Oshima, Koichiro Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 8 p. 1012 - 1014]

Highly selective γ-alkylation of triisopropylsilylallyl anio...

[Muchowski, Joseph M.; Naef, Reto; Maddox, Michael L. Tetrahedron Letters, 1985 , vol. 26, # 44 p. 5375 - 5378]