Silaethene: XIII. Erzeugung von SiC-Doppelbindungen in der Koordinationssphäre von Eisencarbonylkomplexen

…, J Grobe, T Schäfer, B Krebs, M Dartmann

文献索引：Auner, Norbert; Grobe, Joseph; Schaefer, Thomas; Krebs, Bernt; Dartmann, Mechtild Journal of Organometallic Chemistry, 1989 , vol. 363, p. 7 - 24

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被引用次数: 14

摘要

Abstract The suitability of the vinylsilyliron complexes [Cp (CO) 2 Fe] RSi (Cl) CH CH 2 [R= Me (1), Ph (2), Bu t (3), Fe (CO) 2 Cp (4)] and of [Cp (CO) 2 Fe] MeSi (Cl) CMe CH 2 (14) as precursors for the generation of silaethene derivatives has been investigated. The starting compounds 1 to 4 and 14 can be obtained from Me (Vi) SiCl 2, Ph (Vi) SiCl 2, HSiCl 3 and MeSiCl 3, respectively, by judicious combination of published procedures. They have ...