Bulletin of the Chemical Society of Japan

Mechanistic study of the oxidation of substituted benzylamines by N-bromoacetamide

KK Banerji

文献索引：Banerji, Kalyan K. Bulletin of the Chemical Society of Japan, 1988 , vol. 61, p. 3717 - 3722

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被引用次数: 12

摘要

The oxidation of ortho-, meta-, and para-substituted benzylamines by N-bromoacetamide (NBA), to the corresponding benzaldehydes, is first order with respect to NBA and the amine. The pH dependence of the reaction rate suggests that the unprotonated benzylamine is the reductant. There is no effect of added acetamide. NBA itself has been postulated as the reactive oxidizing species. The oxidation of benzylamine-α, α-d 2 exhibited a substantial ...