Photo??oxidative dealkylation of α??alkylbenzyl methyl ethers induced by titanium dioxide in acetonitrile

…, TD Giacco, C Rol, GV Sebastiani

文献索引：Del Giacco, Tiziana; Rol, Cesare; Sebastiani, Giovanni V. Journal of Physical Organic Chemistry, 2003 , vol. 16, # 2 p. 127 - 132

全文：HTML全文

被引用次数: 10

摘要

Abstract TiO 2-sensitised photo-oxidation of α-alkylbenzyl methyl ethers in deaerated CH 3 CN gives the expected corresponding ketone, whereas in an aerated medium a dealkylation compound (methyl benzoate) is obtained as the principal product, with respect to the ketone, or the exclusive product (when the alkyl group is tert-butyl). The product analysis and distribution, together with a qualitative estimate of the relative reactivity, suggest that the ...