Inorganic Chemistry

Ammonolysis of bis (trifluoromethyl) phosphine: a source of new chiral phosphines

AB Burg

文献索引：Burg, A. B. Inorganic Chemistry, 1981 , vol. 20, p. 2739 - 2741

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被引用次数: 20

摘要

Martin and Gould'have shown that the acid dependence of the rate of reaction between Ti (II1) and several salicylato complexes of Co (II1) indicates that chelation of Ti (II1) to the bridging ligand occurs prior to electron transfer (ET). We now report data that demonstrate that a different mechanism operates in the reduction of a corresponding complex of ruthenium (II1).