Base??Catalyzed N N Bond Cleavage of Hydrazones: Synthesis of α??Amino Ketones

HT Tang, YB Zhou, Y Zhu, HC Sun…

文献索引：Tang, Hai-Tao; Zhou, Yun-Bing; Zhu, Yu; Sun, Hong-Chao; Lin, Min; Zhan, Zhuang-Ping Chemistry - An Asian Journal, 2014 , vol. 9, # 5 p. 1278 - 1281

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被引用次数: 2

摘要

Abstract An efficient Cs 2 CO 3-promoted synthesis of α-amino ketones using hydrazines, aldehydes, and α-haloketones as starting materials through a cascade condensation/ nucleophilic substitution/N [BOND] N bond cleavage route is developed. The carbonyl group plays a key role in this novel N [BOND] N bond cleavage process.