Tetrahedron Letters

Cu (I)/TEMPO-catalyzed aerobic oxidative synthesis of imines directly from primary and secondary amines under ambient and neat conditions

B Huang, H Tian, S Lin, M Xie, X Yu, Q Xu

文献索引：Huang, Bo; Tian, Haiwen; Lin, Shoushuai; Xie, Meihua; Yu, Xiaochun; Xu, Qing Tetrahedron Letters, 2013 , vol. 54, # 22 p. 2861 - 2864

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被引用次数: 42

摘要

By catalyst and condition screening, a simple Cu (I)/TEMPO-catalyst system was found to be an active and highly effective catalyst for the aerobic oxidation of amines to imines in open air at room temperature under neat conditions. This new method provided a mild, efficient, and practical alternative for the synthesis of the useful imines directly from primary and secondary amines.