Silylene-to-silanone thermal isomerization

L Linder, A Revis, TJ Barton

文献索引：Linder,L.; Revis,A.; Barton,T.J. Journal of the American Chemical Society, 1986 , vol. 108, p. 2742

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被引用次数: 9

摘要

PPh,. Therefore, while kco* apparently reflects large qualitative differences in reactivity, it appears not to be sensitive to small differences in closely related compounds. On the basis of the above studies, one must conclude that it is not clear whether kco* is related to kinetic or thermodynamic factors and that kco* is useful primarily for predictions when fairly large differences in reactivity are involved. Conclusions Results of this paper show that kco* is a very useful parameter ...